Identification of gamma irradiated lyophilized forest fruits by EPR spectroscopy
Keywords:
EPR spectroscopy, gamma irradiation, lyophilization, forest foodsAbstract
The objective of the present study was to prove the radiation treatment of a set of lyophilized forest fruits (blackberry, blueberry, aronia, strawberry and black elder), irradiated with doses of 2 and 4 kGy by the method of Electronic Paramagnetic Resonance (EPR). A low intensive singlet line was registered for all samples before the irradiation. The results show that after irradiation the intensity of the natural signal is increased, as the so-called “cellulose like” EPR spectrum was registered only for aronia. From the studied lyophilized fruits, according to the protocol for irradiated foods, containing cellulose (EN 1787), and radiation treatment can be proved only for aronia. Protocol EN 13708 for irradiated foods, containing crystalline sugar is not applicable for these samples.
References
Aleksieva, K., L. Georgieva, E. Tzvetkova and N. D. Yordanov, 2009. EPR study on tomatoes before and after gamma-irradiation. Radiat. Phys. Chem., 78: 823-825.
Bayram, G. and H. Delincee, 2004. Identification of irradiated Turkish foodstuffs combining various physical detection methods. Food Control, 15: 81-91.
Bogl, K. W., D. F. Regulla and M. J. Suess, 1988. Health Impact and Control Methods (Identification and Dosimetry) of Irradiated Foods. MMV Medizin, Munchen.
EN 1786, 1997. Detection of Irradiated Food Containing Bone: Analysis by Electron Paramagnetic Resonance, European Committee for Standartization, Brussels.
ЕN 1787, 2000. Detection of irradiated food containing cellulose, method by ESR spectroscopy. European Committee for Standardization, Brussels.
EN 13708, 2001. Detection of irradiated food containing crystalline sugar by ESR spectroscopy. European Committee of Standardization, Brussels.
Gancheva, V. and N. D. Yordanov, 2007. EPR spectroscopy for the detection of irradiated foodstuffs. Food Science, 2: 22-32 (Bg).
Kume, T., M. Furata, S. Todoriki, N. Uenoyama and Y. Kobayashi, 2009. Status of food irradiation in the world. Radiat. Phys. Chem., 78: 222-226.
Mladenova, R. and N. D. Yordanov, 2007. EPR study of the free radicals in lyophilized milk and yogurt, cocoa powder and chocolates. Bulg. Chem. Commun., 39: 128 – 133.
Nikolova, R., A. Djakova, E. Tzvetkova Р., N.Yordanov, K. Dimov and K. Aleksieva, 2007. Studies for detection of gamma irradiated fruits. Food Processing Industry Magazine, 7: 49-51.
Re R. et al., 1999. Antioxidant activity applying an improved ABTS radical cation decolorization assay. Free Rad. Biol. Med., 26:1231-1237.
Yordanov, N. D., K. Aleksieva, A. Dimitrova, L. Georgieva and E. Tzvetkova, 2006. Multifrequency EPR study on freeze-dried fruits before and after X-ray irradiation. Radiat. Phys. Chem., 75: 1069-1074.
Yordanov, N. D. and K. Aleksieva, 2004. X- and Q- band studies on fine powders of irradiated plants. New approach for detection of their radiation history by using Q-band EPR spectrometry. Radiat. Phys. Chem., 69: 59-64.
Yordanov, N. D. and K. Aleksieva, 2009. Preparation and applicability of fresh fruits samples for identification of radiation treatment by EPR. Radiat. Phys. Chem., pp. 451–453.
Yordanov, N. D. and Z. Pachova, 2006. Gamma-irradiated dry fruits. An example of a wide variety of long-time dependent EPR spectra. Spectrochimica Acta, Part A, 63: 891-895.
Vertz, J. and J. Bolton, 1975. Theory and practical application of EPR method. Publ. “Mir”, Moscow (Ru).
Downloads
Published
Issue
Section
License
Copyright (c) 2013 Bulgarian Journal of Agricultural Science

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

